I HAVE THE SAME PROBLEM. Or at least it reads like it. I noticed steam coming from the engine compartment after leaving the carwash. I thought it was a brilliant idea to race my rig home to drain the excess water off and then detail dry LOL. That said white steam was coming out near the rear of the throttle body.
Replaced
thermostat, coolant pump, coolant hoses, serpentine belt (why not), belt tensioner (another why not), oil cooler tube, oil cooler tube seals (one on each side)
Filled with factory recommended coolant and turned the heater on to fill. The engine runs on idle for at least 10 minutes without showing signs of overheating, then - whamo! It starts with the white steam coming out of the rear of the throttle body area.
Any thoughts group? Oh and glad that Matt got his problem solved! I am dealing with a mystery my friends.
2010 HSE non SCH
Los Angeles, CA