What do you think you will gain from adding headers? Actually 5 H.P. or less and a slightly better sound.
To benefit from headers on our engines, you must start with re working the heads and intakes, then add larger injectors and a really good tune.
How many miles on your engine? If over 100,000 miles, your cam will be showing wear on the lobes and without replacing it along with the lifters, you won't see much of any gain in performance unless you go to a custom/non Rover cam shaft.