Seat air bag - disconnect battery.
Before you fool around too much with the seats, remember the seat backs have an air bag inside. As such, disconnect the starting battery and any other batteries you have before you play around too much.
A single hot spot sounds like a breaking, (not broken), heater wire.
I expect that a local seat upholstery shop would have experience with repairing the heating elements in Mercedes, BMW, or perhaps even Ford heated seats.
Almost for certain, you cannot purchase a sensor even it that was the problem. I expect it is a part of the seat heating mat and somehow specific to the Land Rover computer heater control system, which may be Ford or BMW but who knows.
To get at the heater mat, you have to remove the leather seat cover. To remove the leather, you have to remove the seat cushion. To remove the cushion, I think you will have to remove the whole seat/back assembly to get at the 4 Torx screws on the underside of the seat to remove the seat cushion. You may beable to feel for the screws however - probably will be able to get at 3 of them.
This is why de-powering the air bags matters; if not done, you may gain a lot more knowledge of the seat construction than you initially anticipated.